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2,3-Wittig rearrangement

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DbpediaThing
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The [2,3]-Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. Because the reaction is concerted, it exhibits a high degree of stereocontrol, and can be employed early in a synthetic route to establish stereochemistry. The Wittig rearrangement requires strongly basic conditions, however, as a carbanion intermediate is essential. [1,2]-Wittig rearrangement is a competitive process.
2,3-Wittig rearrangement
English Wikipedia http://en.wikipedia.org/wiki/2,3-Wittig_rearrangement
Spanish wikipedia http://es.wikipedia.org/wiki/2,3-Wittig_rearrangement

Conceptual map: 2,3-Wittig rearrangement

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Fecha publicación: 21.4.2015

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